I've personally never had a problem using Tesco fuels, but then, the missus does drive the car and Full Throttle doesnt happen particularly often.
ALL fuels degrade over time, and super unleaded (irrespective of its source) degrades quicker than regular unleaded anyway. Its not like its in the tank for long though, i recon at most the car goes about 2 weeks before needing filled up.
Some people slate supermarket petrol, but for me, its likely got a much higher turnover than buying it from a smaller garage, simply due to the volumes used, as such its likely to be fresh petrol your buying, rather than stuff thats sat in their tanks for weeks or months. All petrol contains additives and suchlike, and lets face it, we're not chemical engineers, so we've really no grounds to comment one way or another on wether they're good or bad.
Sure, we've all heard stories where someones filled up at XYZ supermarket and the car ran like crap afterwards, but i've heard the same things about Esso, BP, Shell etc so its all just the same. Bad fuel is bad fuel, and imo your no more likely to get it from a supermarket than a "normal" garage. I'd much rather fill up at my local tesco, than at the tiny shell garage i pass on the way there that charges £1.40 a litre for V power, because its likely that no-one ever buys VPower from there given its absolutely mental pricing, and so the stuff in the tanks will be ancient.