Does the central locking still operate on the key in the door?
If it does, then it could only be the transmitter / receiver most likely.
If it doesn't, then it could be a fuse or worse!
Depending how technically minded you are, you could check the unit in the boot. I'm not sure whether your car still has vacuum operated locks (quiet (can hear a whirry pump noise from boot when operated) and can see the lock travel smoothly up and down). Check that the vacuum hose is on correctly and all the connectors are still on. (the unit in my '95 A4 is located under the lining of the boot into the drivers side arch. If you have a multimeter and a haynes manual central locking diagram, you could try testing the voltages on each connector.
So I would firstly eliminate what is faulty.
1) Does key operate central locking - if it does the transmitter / receiver suspect
Try a different key fob and check that it is coded to vehicle
- if it doesn't, check fuses etc
if you can hear the whirring noise when you try to lock /
unlock but nothing happens, check vacuum air hoses.
I've no experience of vag-com myself, but I'm sure someone else could spread some light on that!
Let us know how you get on