you cant do much with Agn's but performance exhaust, ram air intake, piggyback ecu, thats what you can do without opening the engine and you should get close or slightly exceed the 110 kw that the stock agu's produce.
Option 2 is port the head, stroke the motor (using the crank from the 2.0 ALT thats in the b6 a4's since it is essentially a stroked ADR/AGN/APG , not sure about the pistons but im pretty sure the ALT has a bigger cylinder bore), but then you are talking money, the same amount of money it would cost to just swap out the motor with an Agu one or if you want to be a bit more unique the 5 cylinder 10 valve (golf 4) AGZ motor will also fit and it produces 110KW just like an Agu and it also uses the 3.82 to 3.8.5 motronic ecu's