I did a lot of research on the net and couldn't find anybody that had found a straightforward Master cylinder upgrade for the S3 /TT.
I tackled the rear brake upgrade by fitting Calipers with a larger piston.I had fitted some TRRS 4 pot Brembo's with 334mm V6 brake discs on the front and found the car was standing on it's nose when braking hard.
The standard rear brakes don't get that much abuse really and having such large discs on the rear isn't required from a heat capacity point of view. You are just moving the caliper out to gain the mechanical advantage 330/256 = 1.29 so about 30% extra braking torque.
https://www.audi-sport.net/xf/threa...ar-g25-660-upgrade.319422/page-4#post-3255700
I fitted rear calipers off an A6 4.2 V8. These are pretty much identical to the standard caliper but have a 43mm piston instead of a 38mm one.
(43x43) / (38x38) = 1.28 so pretty much the same braking force as fitting a 330mm rear disc with a standard caliper.
This restored the braking balance to the car, no longer stands on it's nose when braking hard and seems to work well on the track. I didn't have excessive pedal travel before doing this upgrade, and I know some of the multi pot front brake upgrades can leave you with a lot of pedal travel. Fitting these rear calipers made little difference to the pedal travel on mine.
You don't get to have larger rear discs in the back but you can use standard discs and you get new rear calipers which you may be buying anyway as the existing ones are likely not to be the best.