could be a number of things. this is one of those things that youre gonna have to find out by visually checking.
could be raditor, remove the undertray and inspect.
could be water pump. inspect.
could be cracked expansion bottle. inspect.
could be be expansion bottle cap.
could be cracked/perished hoses.
could be loose jubilee clips.
could be headgasket, coolant getting into combustion chamber and burnt. could be mixing with oil.
the possibilites are endless without some clues.