No you can’t buy it in the U.K. at the pumps. Morrison’s did experiment with it about 5yrs ago or so but quickly pulled the plug as there aren’t enough manufacturer designed flex fuel cars that will allow you to mix.
Aaoils and Demon Tweeks are the only two places you can buy it in at around £5.25-£5.50 a litre. I looked on eBay but couldn’t find another source.
It’s a ballache to run and extreme caution must be used when running it. As in, the tank, pump and lines need to be pretty much empty before filling up and then likewise again before switching back. You’ll run into engine issues on an E85 tune with 99 still in the pump and lines and the same if you have E85 in the pump and lines and then run the 99 tune. I’ve just switched back to 99, went 20 miles past 0 with E85, filled up to max with 99, switched map back to 99, put my foot down on the slip road and at about 80 leptons, hit a brick wall, 4000rpm limp, flashing lights, take your car to workshop message. Got home, scanned it to find a low fuel pressure message. Makes sense now, as E85 needs 30% more fuel flow, it wouldn’t have got that on the 99 map. Cleared the error codes and going to run it about 50 miles on the 99 before going full throttle again.
Would be worse the other way, switch to E85 with 99 still in the lines.
Also running into misfire issues on the APR map on both 99 octane file and E85 file when fuel quantity is low. If the range has less than around 40 miles and you use Launch control, the fuel is thrown to the back of the tank and the pumps cannot supply fuel quick enough so I’ve noticed a few misfires in the 3-4 gearchange shift (only off of Launch control) not driving through 3-4 normally. If I fill up and take my range above 40m remaining, it doesn’t happen. Heard it’s quite common.