Ferodo Premier pads are the dogs danglies for a good "road" pad. I dont rate mintex reds at all, they seem great at first but after a while they seem to "go off" and become a bit ****.
IMO spending money on fancy disks is a waste of time, and has various downsides, just get some standard plain ones from the factors and nail them on. If you want to improve things further, then spend the money on good pads, however most pads which are more aggressive tend to have worse cold performance. 312's and Ferodo Premiers all round is a decent solid setup for most road based cars IMO.
You'll need to ensure your TDI has 288's at the moment. Some earlier cars had 280mm disks instead, and while that doesnt stop you converting to 312's, you cant use the 280mm caliper with the TT/S3 carrier.
You also cant use the TT/S3 caliper, as the piston is smaller than the A4 one.
If you have 288's currently, then you need the TT/S3 carrier, the 312mm B6 A4 3.0 disks, and some new pads.
If you have 280's currently, then you also need a pair of 288 spec A4 front calipers.
Its probably also worth looking at replacing the fluid while your there. I'd recommend ATE Blue.
Also, once its all done, you'll need to bed them in properly to get the best from them.