From what I heard, the best thing for performance is to use good fuel, like Shell V-Power or BP high octane rated fuel. As these fuels burn/explode better with less temperature being generated, which results in your exhaust gases being at lower temp.
Additives don't really give you the power they claim, so the money you save on them can be better used on good fuel, which will guarantee better power and fuel economy.
I would stay away from them.